01 - Preheat oven to 400°F (200°C).
02 - Pat chicken breasts dry. Season evenly on both sides with salt, black pepper, and garlic powder.
03 - In a shallow bowl, combine grated Parmesan cheese, fine breadcrumbs, chopped parsley, and dried oregano. Press each chicken breast firmly into the coating mixture until both sides are thoroughly covered.
04 - Heat 2 tablespoons olive oil in a large ovenproof skillet over medium-high heat. Sear chicken breasts for 2 to 3 minutes per side until golden brown.
05 - Transfer the skillet with seared chicken to the preheated oven. Bake for 18 to 22 minutes, or until internal temperature reaches 165°F (74°C).
06 - While the chicken bakes, combine roasted red bell peppers, garlic clove, olive oil, balsamic vinegar, smoked paprika, salt, and pepper in a blender or food processor. Blend until completely smooth.
07 - Taste the red pepper sauce and adjust seasoning as needed. Gently warm sauce in a small saucepan over low heat, if desired.
08 - Arrange the baked Parmesan-crusted chicken breasts on serving plates. Spoon the warm red pepper sauce generously over each portion and garnish with additional chopped parsley if desired.